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color: rgb(0, 0, 0); font-family: 宋体; line-height: 22px;"> <tbody> <tr> <td style="margin: 0px; padding: 0px;">为了解决硅烷偶联剂对聚烯烃等热塑性塑料缺乏偶联效果的问题,20世纪70年代中期发展了 钛酸酯类偶联剂。这类偶联剂在塑料中有相当好的效果。<br /> <font face="Verdana">钛</font>酸醋偶联剂的通式为(RO)m,Ti(OXR'Y)n,RO基团与无机填料的表面经基、表面吸附水和H＋ 起作用，形成能包围填料单分子层的基团;Ti(OX)为与聚合物原子连接的原子团(粘合基团)，可 为烷氧基、按基、硫酞氧基、磷氧基、亚磷酞氧基、焦磷酞氧基等，该基团是钦酸醋的特性基团 。R'为长链部分，可与聚合物分子缠绕，保证与聚合物的分子的混容;Y是与铁酸醋可进行交联的 官能团，可为不饱和双键、氨基、9基等。m、n为官能团数，可据此控制交联程度.<br /> <a href='http://www.ahhcqx.com/index.php?case=archive&act=list&catid=29' target='_blank'>钛酸酯偶联剂</a>中的长链烃基C12-C,。为亲有机部分，可与聚合物分子链发生缠绕，并借范德 华力结合在一起，这一偶联作用对热塑性的聚烯烃类塑料特别适用。因为长链的缠结，可转移应 力，改变应变，提高冲击强度、剪切强度和伸长率;还可在抗拉强度不大受影响的情况下，增加填充量。长链烃基还能使所接触无机物界面处的表面能改变，粘度下降，高填充聚合物熔体的流 动性良好。</td> </tr> </tbody> </table><div class="clear"></div> </div> <div class="blank30"></div> <div class="blank30"></div> <!--自动调用自定义字段--> <div class="blank20"></div> <div class="blank30"></div> <!-- 投票 --> <script src="/index.php?case=vote&act=view&aid=1289"></script> <!-- 自定义表单开始 --> <!-- 自定义表单结束 --> <script language="JavaScript"> function shutwin(){ window.close(); 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